| 1 |  Antonio Colom Mas (ESP) | Team Katusha | 3.54.49 (36.62 km/h) |
| 2 |  Edvald Boasson Hagen (NOR) | Team Columbia - HTC | 0.56 |
| 3 |  Jérôme Pineau (FRA) | Quick Step | s.t. |
| 4 | Sylvain Chavanel (FRA) | Quick Step | s.t. |
| 5 |  Maxime Monfort (BEL) | Team Columbia - HTC | s.t. |
| 6 |  Morris Possoni (ITA) | Team Columbia - HTC | 1.00 |
| 7 | Mikel Nieve Iturralde (ESP) | Euskaltel - Euskadi | 1.01 |
| 8 | Manuel Vazquez Hueso (ESP) | Murcia - Contentpolis - Ampo | 1.05 |
| 9 |  Paul Martens (GER) | Rabobank | s.t. |
| 10 | Markus Fothen (GER) | Team Milram | s.t. |
| 11 | Tony Martin (GER) | Team Columbia - HTC | 1.06 |
| 12 | Francisco Perez Sanchez (ESP) | Caisse d'Epargne | s.t. |
| 13 |  Roman Kreuziger (CZE) | Liquigas | 1.28 |
| 14 | Ivan Santaromita (ITA) | Liquigas | 1.32 |
| 15 | Juan Manuel Gárate Cepa (ESP) | Rabobank | 2.00 |
| 16 | Inigo Landaluze Intxaurraga (ESP) | Euskaltel - Euskadi | s.t. |
| 17 |  Laurens Ten Dam (NED) | Rabobank | s.t. |
| 18 | Dario Cataldo (ITA) | Quick Step | 2.25 |
| 19 | José Joaquin Rojas Gil (ESP) | Caisse d'Epargne | s.t. |
| 20 | Pablo Lastras Garcia (ESP) | Caisse d'Epargne | 2.35 |
| 21 | Davide Malacarne (ITA) | Quick Step | s.t. |
| 22 | Bert Grabsch (GER) | Team Columbia - HTC | s.t. |
| 23 |  Christian Pfannberger (AUT) | Team Katusha | s.t. |
| 24 | Aitor Perez Arrieta (ESP) | Murcia - Contentpolis - Ampo | s.t. |
| 25 |  Gorazd Stangelj (SLO) | Liquigas | s.t. |
| 26 |  Andrey Amador Bikkazakova (CRC) | Caisse d'Epargne | 2.46 |
| 27 | Rafael Valls Ferri (ESP) | Burgos Monumental | 3.52 |
| 28 | Javier Moreno Bazan (ESP) | Andalucía - Cajasur | 4.18 |
| 29 | David Lopez Garcia (ESP) | Caisse d'Epargne | s.t. |
| 30 | Javier Etxarri Marin (ESP) | Rock Racing | 5.01 |
| 31 | Koos Moerenhout (NED) | Rabobank | s.t. |
| 32 | Aitor Hernandez Gutierrez (ESP) | Euskaltel - Euskadi | s.t. |
| 33 |  Eduard Vorganov (RUS) | Xacobeo - Galicia | s.t. |
| 34 | Johannes Fröhlinger (GER) | Team Milram | s.t. |
| 35 | Marcos Garcia Fernandez (ESP) | Xacobeo - Galicia | 5.04 |
| 36 |  Jonathan Tiernan-Locke (GBR) | Plowman Craven - Madison | 5.47 |
| 37 | Arjen Pieter De Baat (NED) | Van Vliet - Ebh - Elshof | s.t. |
| 38 | Samuel Dumoulin (FRA) | Cofidis, le Crédit en Ligne | s.t. |
| 39 | Marco Pinotti (ITA) | Team Columbia - HTC | 7.23 |
| 40 |  Konstantin Sivtsov (BLR) | Team Columbia - HTC | s.t. |
| 41 | Björn Thurau (GER) | Elk Haus - Simplon | s.t. |
| 42 | Andreas Schillinger (GER) | Nutrixxion - Sparkasse | s.t. |
| 43 | Gerhard Trampusch (AUT) | Elk Haus - Simplon | s.t. |
| 44 | Esteban Plaza Mira (ESP) | Andalucía - Cajasur | s.t. |
| 45 | Javier Ramirez Abeja (ESP) | Andalucía - Cajasur | s.t. |
| 46 | Pedro Fernandez Hermida (ESP) | Xacobeo - Galicia | s.t. |
| 47 | Gustavo Dominguez Lemos (ESP) | Xacobeo - Galicia | s.t. |
| 48 | Eriz Ruiz De Erentxun Antetara (ESP) | Orbea - Oreka S.d.a | s.t. |
| 49 | Sergio Dominguez Munoz (ESP) | Murcia - Contentpolis - Ampo | s.t. |
| 50 | Dries Devenyns (BEL) | Quick Step | s.t. |
| 51 | Jorge Azanza Soto (ESP) | Euskaltel - Euskadi | s.t. |
| 52 | Francisco Javier Aramendia Llorente (ESP) | Euskaltel - Euskadi | s.t. |
| 53 | Josu Agirre Aseginolaza (ESP) | Euskaltel - Euskadi | s.t. |
| 54 | Bingen Fernandez Bustinza (ESP) | Cofidis, le Crédit en Ligne | s.t. |
| 55 | Juan Jose Oroz Ugalde (ESP) | Euskaltel - Euskadi | s.t. |
| 56 | Romain Sicard (FRA) | Orbea - Oreka S.d.a | s.t. |
| 57 | Matteo Tosatto (ITA) | Quick Step | 9.27 |
| 58 | Frederik Willems (BEL) | Liquigas | s.t. |
| 59 | Manuel Calvente Gorbas (ESP) | Andalucía - Cajasur | 9.30 |
| 60 | Joan Sebastian Horrach Rippoll (ESP) | Team Katusha | 11.37 |
| 61 | David Arroyo Duran (ESP) | Caisse d'Epargne | s.t. |
| 62 | Martin Müller (GER) | Team Milram | s.t. |
| 63 | Matthias Russ (GER) | Team Milram | s.t. |
| 64 | Jesus Rosendo Prado (ESP) | Andalucía - Cajasur | s.t. |
| 65 | Enrico Franzoi (ITA) | Liquigas | s.t. |
| 66 | Serguei Klimov (RUS) | Team Katusha | s.t. |
| 67 | Vladimir Karpets (RUS) | Team Katusha | s.t. |
| 68 | Joaquim Rodríguez Oliver (ESP) | Caisse d'Epargne | s.t. |
| 69 | Joseba Larralde Alzugaray (ESP) | Orbea - Oreka S.d.a | s.t. |
| 70 | Diego Gallego Arnaiz (ESP) | Burgos Monumental | s.t. |
| 71 |  Hubert Schwab (SUI) | Quick Step | s.t. |
| 72 | Dmitry Kozontchuk (RUS) | Rabobank | s.t. |
| 73 | Juan Javier Estrada Ruiz (ESP) | Andalucía - Cajasur | s.t. |
| 74 | Alexandre Botcharov (RUS) | Team Katusha | s.t. |
| 75 | Adrian Palomares Villaplana (ESP) | Murcia - Contentpolis - Ampo | s.t. |
| 76 | Arnold Jeannesson (FRA) | Caisse d'Epargne | s.t. |
| 77 | Dirk Müller (GER) | Nutrixxion - Sparkasse | 11.45 |
| 78 | Alejandro Paleo Mosquera (ESP) | Xacobeo - Galicia | 12.11 |
| 79 | Iban Mayoz Etxebarria (ESP) | Xacobeo - Galicia | 12.23 |
| 80 | Juan Francisco Mouron Doldan (ESP) | Xacobeo - Galicia | s.t. |
| 81 | Mauro Facci (ITA) | Quick Step | 13.10 |
| 82 | Julian Sanchez Pimienta (ESP) | Murcia - Contentpolis - Ampo | 13.15 |
| 83 | Dennis Pohl (GER) | Kuota - Indeland | 14.36 |
| 84 | Bram Schmitz (NED) | Van Vliet - Ebh - Elshof | s.t. |
| 85 | Rikke Dijkxhoorn (NED) | Van Vliet - Ebh - Elshof | 14.38 |
| 86 | Jos Van Emden (NED) | Rabobank | s.t. |
| 87 | Nick Nuyens (BEL) | Rabobank | 14.40 |
| 88 | Manuel Quinziato (ITA) | Liquigas | s.t. |
| 89 |  Peter Velits (SVK) | Team Milram | s.t. |
| 90 |  Sylvester Szmyd (POL) | Liquigas | s.t. |
| 91 | Alberto Losada Alguacil (ESP) | Caisse d'Epargne | s.t. |
| 92 | Gorka Verdugo Marcotegui (ESP) | Euskaltel - Euskadi | s.t. |
| 93 | Jose Ruiz Sanchez (ESP) | Andalucía - Cajasur | s.t. |
| 94 | Vladimir Isaychev (RUS) | Xacobeo - Galicia | 14.52 |
| 95 | Kurt Hovelynck (BEL) | Quick Step | s.t. |
| 96 | Harald Starzengruber (AUT) | Elk Haus - Simplon | s.t. |
| 97 | Nicolas Jonathan Castroviejo (ESP) | Orbea - Oreka S.d.a | 15.46 |
| 98 | Ronan Van Zandbeek (NED) | Van Vliet - Ebh - Elshof | 17.43 |
| 99 | Evan Oliphant (GBR) | Endura Racing | s.t. |
| 100 | Stephen Adams (GBR) | Plowman Craven - Madison | s.t. |
| 101 | Tom Stamsnijder (NED) | Rabobank | s.t. |
| 102 | Sjoerd Kouwenhoven (NED) | Van Vliet - Ebh - Elshof | s.t. |
| 103 | Eneko Echeverz Carte (ESP) | | s.t. |
| 104 | Andres Sergio De Lis (ESP) | Euskaltel - Euskadi | s.t. |
| 105 | Stijn Devolder (BEL) | Quick Step | s.t. |
| 106 | Stéphane Augé (FRA) | Cofidis, le Crédit en Ligne | 17.46 |
| 107 | Jean-Mitja Schlüter (GER) | Nutrixxion - Sparkasse | s.t. |
| 108 | Lars Vierbergen (NED) | Van Vliet - Ebh - Elshof | s.t. |
| 109 | Daniel Sesma Sorbet (ESP) | Orbea - Oreka S.d.a | s.t. |
| 110 | Antonio Piedra Perez (ESP) | Andalucía - Cajasur | 20.45 |
| 111 | José Antonio Redondo Ramos (ESP) | Andalucía - Cajasur | s.t. |
| 112 | Rafael Serrano Fernandez (ESP) | Murcia - Contentpolis - Ampo | s.t. |
| 113 | Andres Avelino Antuña Coro (ESP) | Burgos Monumental | s.t. |
| 114 | Angel Madrazo Ruiz (ESP) | Caisse d'Epargne | 20.47 |
| 115 | Claudio José Casas Gallego (ESP) | Andalucía - Cajasur | 23.52 |
| 116 | Gorka Izagirre Insausti (ESP) | Murcia - Contentpolis - Ampo | s.t. |
| 117 | Bas Stamsnijder (NED) | Van Vliet - Ebh - Elshof | 26.08 |
| 118 |  Robbie McEwen (AUS) | Team Katusha | 30.54 |
| 119 | Andoni Blazquez Berasarte (ESP) | Orbea - Oreka S.d.a | 3 |
