| 1 |  Jose Ivan Gutierrez Palacios (ESP) | Caisse d'Epargne | 25.34 (50.691 km/h) |
| 2 |  Alexander Vinokourov (KAZ) | Astana - Würth Team | 0.10 |
| 3 |  Michael Rich (GER) | Gerolsteiner | 0.14 |
| 4 | Santos Gonzalez Capilla (ESP) | Tres Molinos Resort | 0.15 |
| 5 | Markus Fothen (GER) | Gerolsteiner | 0.26 |
| 6 | Vicente David Bernabéu Armengol (ESP) | Comunidad Valenciana | 0.29 |
| 7 |  Marzio Bruseghin (ITA) | Lampre - Fondital | 0.30 |
| 8 |  Jurgen Van Den Broeck (BEL) | Discovery Channel Pro Cycling Team | s.t. |
| 9 |  Jan Hruska (CZE) | Tres Molinos Resort | 0.40 |
| 10 | Juan Gomis Lopez (ESP) | Comunidad Valenciana | 0.43 |
| 11 | Ángel Vicioso Arcos (ESP) | Astana - Würth Team | s.t. |
| 12 | Egoi Martinez De Esteban (ESP) | Discovery Channel Pro Cycling Team | 0.46 |
| 13 |  Sergiy Matveyev (UKR) | Panaria - Navigare | 0.50 |
| 14 | José Luis Martinez Jimenez (ESP) | Comunidad Valenciana | 0.55 |
| 15 | Marc Wauters (BEL) | Rabobank | 1.02 |
| 16 |  Beat Zberg (SUI) | Gerolsteiner | 1.04 |
| 17 |  Fumiyuki Beppu (JAP) | Discovery Channel Pro Cycling Team | s.t. |
| 18 | Frank Vandenbroucke (BEL) | Acqua & Sapone - Caffe Mokambo | 1.05 |
| 19 | Alejandro Valverde Belmonte (ESP) | Caisse d'Epargne | 1.06 |
| 20 |  Denis Menchov (RUS) | Rabobank | 1.07 |
| 21 | Francisco Perez Sanchez (ESP) | Caisse d'Epargne | 1.10 |
| 22 | Aketza Pena Iza (ESP) | Euskaltel - Euskadi | 1.17 |
| 23 |  Florent Brard (FRA) | Caisse d'Epargne | 1.19 |
| 24 |  Marc De Maar (AHO) | Rabobank | 1.22 |
| 25 | Juan Carlos Dominguez Dominguez (ESP) | Unibet.com | 1.24 |
| 26 | Damiano Cunego (ITA) | Lampre - Fondital | 1.27 |
| 27 | Gustavo César Veloso (ESP) | Kaiku | 1.30 |
| 28 | Jose Luis Carrasco Gamiz (ESP) | Caisse d'Epargne | 1.32 |
| 29 | Luis Pasamontes Rodriguez (ESP) | Caico | s.t. |
| 30 | Carlos Garcia Quesada (ESP) | Unibet.com | s.t. |
| 31 | Jesus Del Nero Montes (ESP) | Tres Molinos Resort | 1.33 |
| 32 | Alberto Losada Alguacil (ESP) | Kaiku | s.t. |
| 33 |  Sylvester Szmyd (POL) | Rabobank | 1.34 |
| 34 |  Trent Lowe (AUS) | Discovery Channel Pro Cycling Team | s.t. |
| 35 | Manuel Beltran Martinez (ESP) | Discovery Channel Pro Cycling Team | s.t. |
| 36 | Carlos Castaño Panadero (ESP) | Kaiku | 1.36 |
| 37 |  Pieter Weening (NED) | Rabobank | s.t. |
| 38 | Mikel Pradera Rodriguez (ESP) | Caisse d'Epargne | 1.37 |
| 39 |  Tadej Valjavec (SLO) | Lampre - Fondital | 1.41 |
| 40 | Igor Antón Hernandez (ESP) | Euskaltel - Euskadi | 1.44 |
| 41 |  Georg Totschnig (AUT) | Gerolsteiner | 1.46 |
| 42 | Laurens Ten Dam (NED) | Unibet.com | 1.49 |
| 43 | Matthew White (AUS) | Discovery Channel Pro Cycling Team | 1.50 |
| 44 | Pablo Urtasun Perez (ESP) | Kaiku | 1.51 |
| 45 | José Antonio Banos Ballester (ESP) | Tres Molinos Resort | 1.52 |
| 46 | Niels Scheuneman (NED) | Rabobank | 1.53 |
| 47 | Giuliano Figueras (ITA) | Lampre - Fondital | 1.55 |
| 48 | Ruben Perez Moreno (ESP) | Euskaltel - Euskadi | 1.56 |
| 49 | Gorazd Stangelj (SLO) | Lampre - Fondital | 2.00 |
| 50 |  José Adrian Bonilla (CRC) | Comunidad Valenciana | 2.01 |
| 51 | Benat Albizuri Aransono (ESP) | Euskaltel - Euskadi | s.t. |
| 52 | Ivan Gilmartin Hernangomez (ESP) | Kaiku | 2.05 |
| 53 | Emanuele Sella (ITA) | Panaria - Navigare | 2.18 |
| 54 | Joan Sebastian Horrach Rippoll (ESP) | Caisse d'Epargne | 2.21 |
| 55 | José Mario Almagro (ESP) | Saunier Duval - Prodir | s.t. |
| 56 | José Antonio Lopez Gil (ESP) | Kaiku | 2.23 |
| 57 | Marcos Antonio Serrano Rodriguez (ESP) | Astana - Würth Team | 2.24 |
| 58 | José Miguel Elías Galindo (ESP) | Relax - Gam | 2.26 |
| 59 | Paolo Tiralongo (ITA) | Lampre - Fondital | s.t. |
| 60 | Joseba Zubeldia Aguirre (ESP) | Euskaltel - Euskadi | 2.28 |
| 61 | Anton Luengo Celaya (ESP) | Euskaltel - Euskadi | s.t. |
| 62 | Jaume Rovira Pous (ESP) | Andalucia - Paul Versan | 2.29 |
| 63 | David Muñoz Baron (ESP) | Comunidad Valenciana | s.t. |
| 64 |  Michael Rasmussen (DEN) | Rabobank | 2.30 |
| 65 | Carlos Abellan Ossenbach (ESP) | Astana - Würth Team | s.t. |
| 66 | Isidro Cerrato Lopez (ESP) | Tres Molinos Resort | 2.32 |
| 67 | Max Van Heeswijk (NED) | Discovery Channel Pro Cycling Team | 2.35 |
| 68 | Theo Eltink (NED) | Rabobank | 2.40 |
| 69 | Francisco Cabello Luque (ESP) | Andalucia - Paul Versan | 2.43 |
| 70 | Mario De Sarraga Orviz (ESP) | Relax - Gam | 2.44 |
| 71 | Unai Uribarri (ESP) | Euskaltel - Euskadi | s.t. |
| 72 | Pedro Luis Marichalar Fernandez (ESP) | Andalucia - Paul Versan | 2.46 |
| 73 | Guennadi Mikhailov (RUS) | Discovery Channel Pro Cycling Team | 2.47 |
| 74 | Julian Sanchez Pimienta (ESP) | Comunidad Valenciana | s.t. |
| 75 | Thorwald Veneberg (NED) | Rabobank | 2.54 |
| 76 | Heinrich Haussler (GER) | Gerolsteiner | s.t. |
| 77 | Angel Castresana Del Val (ESP) | Unibet.com | s.t. |
| 78 | Francisco José Terciado Sacedo (ESP) | Relax - Gam | 2.56 |
| 79 | José Cayetano Julia Cegarra (ESP) | Quick Step - Innergetic | s.t. |
| 80 | José Luis Martinez Jimenez (ESP) | Comunidad Valenciana | 3.02 |
| 81 | Oscar Garcia Casarrubios Pintor (ESP) | Relax - Gam | s.t. |
| 82 | Ivan Santos Martinez (ESP) | Astana - Würth Team | 3.03 |
| 83 | Marco Marzano (ITA) | Lampre - Fondital | 3.05 |
| 84 | Kurt Van De Wouwer (BEL) | Unibet.com | 3.06 |
| 85 | Nacor Burgos Rojo (ESP) | Relax - Gam | 3.09 |
| 86 | Dionisio Galparsoro Martinez (ESP) | Kaiku | 3.15 |
| 87 | Claudio José Casas Gallego (ESP) | Comunidad Valenciana | 3.16 |
| 88 | Thomas Fothen (GER) | Gerolsteiner | 3.26 |
| 89 | Peter Wrolich (AUT) | Gerolsteiner | 3.27 |
| 90 | Javier Ramirez Abeja (ESP) | Astana - Würth Team | 3.32 |
| 91 | Francisco Jose Martinez Perez (ESP) | Andalucia - Paul Versan | 3.36 |
| 92 | Julio Garcia Bravo (ESP) | Tres Molinos Resort | 3.39 |
| 93 | Iban Mayo Díez (ESP) | Euskaltel - Euskadi | 3.47 |
| 94 | Jesus Buendia Romero (ESP) | Tres Molinos Resort | 3.51 |
| 95 | Ezequiel Mosquera Miguez (ESP) | Comunidad Valenciana | s.t. |
| 96 | José Antonio Banos Ballester (ESP) | Tres Molinos Resort | 3.56 |
| 97 | Baden Cooke (AUS) | Unibet.com | 3.57 |
| 98 |  Ariel Maximiliano Richeze Araquistaín (ARG) | Panaria - Navigare | 3.58 |
| 99 | Manuel Vazquez Hueso (ESP) | Andalucia - Paul Versan | 4.02 |
| 100 | David Etxebarria Alkorta (ESP) | Astana - Würth Team | s.t. |
| 101 | Angel Vallejo Domínguez (ESP) | Relax - Gam | 4.06 |
| 102 | Manuel Ortega Ocana (ESP) | Andalucia - Paul Versan | 4.11 |
| 103 | Domenico Pozzovivo (ITA) | Panaria - Navigare | 4.23 |
| 104 | Angel Edo Alsina (ESP) | Andalucia - Paul Versan | 4.34 |
| 105 |  Miguel Angel Rubiano Chavez (COL) | Panaria - Navigare | 4.43 |
| 106 | Aitor Galdos Alonso (ESP) | Panaria - Navigare | 4.54 |
| 107 | Francisco José Lara Ruiz (ESP) | Andalucia - Paul Versan | 4.56 |
| 108 |  Julio Alberto Perez Cuapio (MEX) | Panaria - Navigare | 5.19 |
| 109 | Sergio Dominguez Rodriguez (ESP) | Tres Molinos Resort | 25 |
